| Advances in transition metal (Pd, Ni, Fe)-catalyzed cross-coupling reactions using alkyl-organometallics as reaction partners R Jana, TP Pathak, MS Sigman Chemical reviews 111 (3), 1417-1492, 2011 | 2028 | 2011 |
| Schiff base catalysts for the asymmetric Strecker reaction identified and optimized from parallel synthetic libraries MS Sigman, EN Jacobsen Journal of the American Chemical Society 120 (19), 4901-4902, 1998 | 1371 | 1998 |
| A general catalyst for the asymmetric Strecker reaction MS Sigman, P Vachal, EN Jacobsen Angewandte Chemie 112 (7), 1336-1338, 2000 | 611 | 2000 |
| Exploiting non-covalent π interactions for catalyst design AJ Neel, MJ Hilton, MS Sigman, FD Toste Nature 543 (7647), 637-646, 2017 | 588 | 2017 |
| Ligand-modulated palladium-catalyzed aerobic alcohol oxidations MS Sigman, DR Jensen Accounts of chemical research 39 (3), 221-229, 2006 | 587 | 2006 |
| Substrate channelling as an approach to cascade reactions I Wheeldon, SD Minteer, S Banta, SC Barton, P Atanassov, M Sigman Nature chemistry 8 (4), 299-309, 2016 | 548 | 2016 |
| Recent advances in homogeneous transition metal-catalyzed aerobic alcohol oxidations MJ Schultz, MS Sigman tetrahedron 62 (35), 8227-8241, 2006 | 480 | 2006 |
| Enantioselective addition of hydrogen cyanide to imines catalyzed by a chiral (salen) Al (III) complex MS Sigman, EN Jacobsen Journal of the American Chemical Society 120 (21), 5315-5316, 1998 | 448 | 1998 |
| Enantioselective Heck arylations of acyclic alkenyl alcohols using a redox-relay strategy EW Werner, TS Mei, AJ Burckle, MS Sigman Science 338 (6113), 1455-1458, 2012 | 419 | 2012 |
| Mechanistic approaches to palladium-catalyzed alkene difunctionalization reactions KH Jensen, MS Sigman Organic & biomolecular chemistry 6 (22), 4083-4088, 2008 | 416 | 2008 |
| A Well‐Defined Complex for Palladium‐Catalyzed Aerobic Oxidation of Alcohols: Design, Synthesis, and Mechanistic Considerations DR Jensen, MJ Schultz, JA Mueller, MS Sigman Angewandte Chemie International Edition 42 (32), 3810-3813, 2003 | 388 | 2003 |
| Enantioselective construction of remote quaternary stereocentres TS Mei, HH Patel, MS Sigman Nature 508 (7496), 340-344, 2014 | 387 | 2014 |
| Palladium-catalyzed enantioselective oxidations of alcohols using molecular oxygen DR Jensen, JS Pugsley, MS Sigman Journal of the American Chemical Society 123 (30), 7475-7476, 2001 | 374 | 2001 |
| Applications of ortho-Quinone Methide Intermediates in Catalysis and Asymmetric Synthesis TP Pathak, MS Sigman The Journal of organic chemistry 76 (22), 9210-9215, 2011 | 329 | 2011 |
| The development of multidimensional analysis tools for asymmetric catalysis and beyond MS Sigman, KC Harper, EN Bess, A Milo Accounts of chemical research 49 (6), 1292-1301, 2016 | 308 | 2016 |
| A synthetic chemist's guide to electroanalytical tools for studying reaction mechanisms C Sandford, MA Edwards, KJ Klunder, DP Hickey, M Li, K Barman, ... Chemical science 10 (26), 6404-6422, 2019 | 284 | 2019 |
| Recent advancements and challenges of palladium II-catalyzed oxidation reactions with molecular oxygen as the sole oxidant KM Gligorich, MS Sigman Chemical communications, 3854-3867, 2009 | 269 | 2009 |
| Predictive and mechanistic multivariate linear regression models for reaction development CB Santiago, JY Guo, MS Sigman Chemical science 9 (9), 2398-2412, 2018 | 261 | 2018 |
| Multidimensional steric parameters in the analysis of asymmetric catalytic reactions KC Harper, EN Bess, MS Sigman Nature chemistry 4 (5), 366-374, 2012 | 257 | 2012 |
| Elucidating the significance of β-hydride elimination and the dynamic role of acid/base chemistry in a palladium-catalyzed aerobic oxidation of alcohols JA Mueller, CP Goller, MS Sigman Journal of the American Chemical Society 126 (31), 9724-9734, 2004 | 251 | 2004 |
